1 · Electrostatic Potential
P1 · every yearThe definition that everything hangs on
Potential at a point = work done by an external agent to bring a unit positive charge from infinity to that point, slowly (no kinetic energy gained).
Standard results — memorise the whole column
| Charge configuration | Potential V | Field E | Watch out |
|---|---|---|---|
| Point charge q at distance r | kq/r | kq/r² | V carries the sign of q; E is magnitude |
| Group of charges | Σ kqi/ri (scalar sum) | vector sum | V can be 0 where E ≠ 0, and vice-versa |
| Dipole, general point (r ≫ a) | kp cosθ / r² | (kp/r³)√(1+3cos²θ) | θ measured from +q side of dipole axis |
| Dipole — axial (θ = 0) | kp/r² | 2kp/r³ | maximum V |
| Dipole — equatorial (θ = 90°) | 0 | kp/r³ | V = 0 but E ≠ 0 — classic trap |
| Charged spherical shell (R), outside | kq/r | kq/r² | behaves like point charge at centre |
| Shell, on surface | kq/R | kq/R² | V continuous, E jumps |
| Shell, inside | kq/R (constant) | 0 | V ≠ 0 inside even though E = 0 |
| Solid non-conducting sphere, inside | kq(3R²−r²)/2R³ | kqr/R³ | Vcentre = 1.5 × Vsurface |
| Infinite line charge λ | −2kλ ln r + C | 2kλ/r | no zero at infinity — only ΔV meaningful |
k = 1/4πε₀ = 9 × 10⁹ N m² C⁻² · ε₀ = 8.854 × 10⁻¹² C² N⁻¹ m⁻²
- E = 0, V ≠ 0 → inside a charged shell / conductor
- E ≠ 0, V = 0 → equatorial point of a dipole; midpoint between +q and −q
- E = 0, V = 0 → far away (infinity)
- E ≠ 0, V ≠ 0 → ordinary point near a single charge
2 · Equipotential Surfaces & E = −dV/dr
P1Five properties — one is asked almost every year
- Work done in moving a charge on an equipotential surface = zero (any path).
- Field is always perpendicular to the equipotential surface.
- Field points from high V to low V (direction of steepest fall).
- Two equipotential surfaces can never intersect (a point would need two potentials).
- Surfaces are closer together where E is stronger; equally spaced & parallel in a uniform field.
3 · Electrostatic Potential Energy
P1Dipole in a uniform external field — the whole set
| θ | 0° | 90° | 180° |
|---|---|---|---|
| U | −pE (minimum) | 0 | +pE (maximum) |
| τ | 0 | pE (maximum) | 0 |
| Equilibrium | stable | — | unstable |
4 · Conductors, Dielectrics & Polarisation
P2Conductor in an electrostatic field
- Einside = 0 (free electrons rearrange until they cancel the applied field)
- Entire conductor is one equipotential volume; surface is an equipotential
- All excess charge resides on the outer surface
- Just outside: E = σ/ε₀, normal to the surface
- σ is largest where curvature is largest (sharp points) → corona discharge, lightning rods
- Electrostatic shielding: field inside a cavity (no charge in it) is zero, whatever happens outside
Dielectrics
- Non-polar (H₂, O₂, CO₂, CH₄, benzene): zero dipole moment until a field is applied
- Polar (H₂O, HCl, NH₃): permanent dipole moment, randomly oriented until a field aligns them
- Polarisation P = χe ε₀ E; K = 1 + χe (K ≥ 1 always)
- Net field inside: E = E₀/K — reduced, never reversed
- Bound surface charge σb = P; Einduced = E₀(1 − 1/K)
- Conductor = dielectric with K → ∞
5 · Capacitance
P1 · numerical-heavy| Capacitor | Capacitance | Key point |
|---|---|---|
| Isolated sphere, radius R | C = 4πε₀R = R/k | Earth: C ≈ 711 μF |
| Parallel plate, vacuum | C₀ = ε₀A/d | E = σ/ε₀ between plates, V = Ed |
| Fully filled with dielectric K | C = Kε₀A/d = KC₀ | rises K-fold |
| Dielectric slab thickness t < d | C = ε₀A / (d − t + t/K) | position of slab is irrelevant |
| Conducting slab thickness t | C = ε₀A / (d − t) | put K → ∞ in the row above |
| Two dielectrics stacked (⊥ to plates) | series: d₁/K₁ + d₂/K₂ in denominator | same charge through both |
| Two dielectrics side-by-side (∥) | C = ε₀(K₁A₁ + K₂A₂)/d | same voltage across both |
| Spherical capacitor (a inside, b outside) | C = 4πε₀ ab/(b − a) | — |
6 · Series and Parallel Combinations
P1| Quantity | Series | Parallel |
|---|---|---|
| Same for all | Charge Q | Voltage V |
| Equivalent C | 1/C = 1/C₁ + 1/C₂ + … | C = C₁ + C₂ + … |
| Two capacitors | C = C₁C₂/(C₁+C₂) | C = C₁ + C₂ |
| Ceq compared to members | smaller than the smallest | larger than the largest |
| Voltage division | V₁ = V·C₂/(C₁+C₂) — inverse to C | equal |
| Charge division | equal | Q₁ = Q·C₁/(C₁+C₂) — direct to C |
| n identical capacitors C | C/n | nC |
Redistribution when two charged capacitors are joined
7 · Energy Stored & Energy Density
P18 · Capacitor Lab — the question you keep losing
Fix this tonightThe single most common capacitor mistake is answering an "isolated capacitor" question with "battery-connected" logic. Slide the parameters and toggle the switch to watch which quantity stays pinned.
Parallel-plate capacitor — what stays constant?
Base state: A = 100 cm², d = 2.0 mm, air, connected to a 12 V battery.
| Action | Battery CONNECTED (V constant) | Battery REMOVED (Q constant) |
|---|---|---|
| Insert dielectric K | C ↑K · Q ↑K · V — · E — · U ↑K | C ↑K · Q — · V ↓K · E ↓K · U ↓K |
| Increase separation d | C ↓ · Q ↓ · V — · E ↓ · U ↓ | C ↓ · Q — · V ↑ · E unchanged · U ↑ |
| Increase area A | C ↑ · Q ↑ · V — · E — · U ↑ | C ↑ · Q — · V ↓ · E ↓ · U ↓ |
9 · Current Electricity — Drift Velocity
P1 · in portionThe physical picture
Free electrons in a metal move at ~10⁵–10⁶ m s⁻¹ randomly (thermal speed), colliding with lattice ions every relaxation time τ ≈ 10⁻¹⁴ s. With no field the average velocity is zero. Switch on a field and a small steady drift of ~10⁻⁴ m s⁻¹ superposes on the random motion — that drift is the current.
- vd ∝ I and vd ∝ E — directly
- vd ∝ 1/A — thinner wire, faster drift (same current)
- vd ∝ 1/n — more free electrons, slower drift
- vd is independent of the length if E is fixed; but for a fixed V, vd ∝ 1/L
- Series wires of different area carry the same I, so vd differs; the thin part has larger vd, E and J
Number-sense worth carrying into the hall
- Copper: n ≈ 8.5 × 10²⁸ m⁻³ free electrons (one per atom)
- For I = 1 A in a 1 mm² copper wire: vd ≈ 0.07 mm s⁻¹ — of order 10⁻⁴ m s⁻¹
- Thermal speed ≈ 10⁵ m s⁻¹ → drift is ~10⁹ times smaller
- τ ≈ 10⁻¹⁴ s, mean free path ≈ few nm
- 1 A = 1 C s⁻¹ = 6.25 × 10¹⁸ electrons per second
10 · Ohm's Law — and where it breaks
P1V–I characteristic — ohmic vs non-ohmic
Tap a conductor. Ohmic devices give a straight line through the origin; anything else is non-ohmic.
Limitations of Ohm's law — four standard graphs
| Case | Behaviour | Example |
|---|---|---|
| V not ∝ I | curve, not a straight line | diode, bulb filament (R rises with heat) |
| V–I relation depends on sign of V | asymmetric — conducts one way only | p-n junction diode |
| More than one I for the same V | S-shaped / negative-resistance region | GaAs, thyristor |
| Non-linear + direction-dependent | — | electrolytes, vacuum tubes |
Resistivity — what it does and doesn't depend on
| Resistance R | Resistivity ρ | |
|---|---|---|
| Depends on length & area? | Yes (R = ρL/A) | No — material property |
| Depends on temperature? | Yes | Yes |
| SI unit | ohm (Ω) | Ω m |
| Formula | R = ρL/A | ρ = m/(ne²τ) |
| Material | α | On heating | Reason |
|---|---|---|---|
| Metals (Cu, Ag, Al) | positive, ~10⁻³ K⁻¹ | ρ increases | τ falls (more lattice vibration); n almost constant |
| Semiconductors (Si, Ge, C) | negative | ρ decreases | n rises exponentially — beats the fall in τ |
| Insulators | negative, large | ρ decreases | same reason as semiconductors |
| Alloys — nichrome, manganin, constantan | nearly zero | almost unchanged | used for standard resistors & heating elements |